抄録
A novel hydrogen-bonded metal-organic framework (H-MOF) [Co(HL)2](DMF)1.2(H2O)2.4 (1·solv), in which L = 2,2′:6′,2′′-terpyridine-5,5"-diyl biscarboxylate, was prepared. An intermolecular single H-bond between carboxy and carboxylate sites was present in this compound. The crystal structure of 1·solv showed a 4-fold interpenetrating H-bonded diamond framework. After the desorption of the crystal solvents, 1·desolv exhibited normal and reverse spin-crossover (SCO) behaviours, providing an asymmetric thermal hysteresis loop.
本文言語 | English |
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ページ(範囲) | 5034-5040 |
ページ数 | 7 |
ジャーナル | Dalton Transactions |
巻 | 51 |
号 | 13 |
DOI | |
出版ステータス | Published - 8 3月 2022 |