Hydrogen-bonded cobalt(ii)-organic framework: normal and reverse spin-crossover behaviours

研究成果: Article査読

18 被引用数 (Scopus)

抄録

A novel hydrogen-bonded metal-organic framework (H-MOF) [Co(HL)2](DMF)1.2(H2O)2.4 (1·solv), in which L = 2,2′:6′,2′′-terpyridine-5,5"-diyl biscarboxylate, was prepared. An intermolecular single H-bond between carboxy and carboxylate sites was present in this compound. The crystal structure of 1·solv showed a 4-fold interpenetrating H-bonded diamond framework. After the desorption of the crystal solvents, 1·desolv exhibited normal and reverse spin-crossover (SCO) behaviours, providing an asymmetric thermal hysteresis loop.

本文言語English
ページ(範囲)5034-5040
ページ数7
ジャーナルDalton Transactions
51
13
DOI
出版ステータスPublished - 8 3月 2022

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