Highly selective CO2 electrolysis in aqueous media by a water-soluble cobalt dimethyl-bipyridine complex

Tomiko M. Suzuki, Kengo Nagatsuka, Takamasa Nonaka, Yuichi Yamaguchi, Naonari Sakamoto, Takeshi Uyama, Keita Sekizawa, Akihiko Kudo, Takeshi Morikawa

研究成果: Article査読

1 被引用数 (Scopus)

抄録

A water-soluble Co complex with dimethyl-bipyridine ligands reduced CO2 to CO electrochemically with almost 100% selectivity at −0.80 V vs. NHE in an aqueous medium (pH 6.8) without an organic solvent. The reaction overpotential was 270 mV. A possible CO formation mechanism was discussed based on experiments and calculations.

本文言語English
ページ(範囲)12318-12321
ページ数4
ジャーナルChemical Communications
59
82
DOI
出版ステータスPublished - 20 9月 2023

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