@article{89a82be934374d4686fb475476201636,
title = "Galvinoxyl-inspired dinitronyl nitroxide: structural, magnetic, and theoretical studies",
abstract = "A novel galvinoxyl-inspired dinitronyl nitroxide (1) has been synthesized. Structural analysis revealed that 1 exhibited a resonance structure, resulting from p-benzoquinonediimine N,N′-dioxide and N-phenyl nitroxide moieties. The magnetic study revealed an intramolecular exchange-coupling constant J/kB of −761(3) K in H = −J(S1·S2 + S2·S3), indicating a ground doublet state. Theoretical calculations suggested not only the strong intramolecular antiferromagnetic coupling but also a unique electron configuration owing to a remarkable spin polarization effect.",
author = "Takuya Kanetomo and Sayaka Ono and Yusuke Fukushima and Yuta Takenouchi and Masaya Enomoto",
note = "Funding Information: This study was financially supported by KAKENHI (JSPS, 20K22538). Prof. Takayuki Ishida (The University of Electro-Communications) kindly lent HPLC (Japan Analytical Industry, 1H + 1H GPC columns; a flow rate of 3.5 mL min−1) for the isolation of 1. The crystallography study for 1 was supported by “Advanced Research Infrastructure for Materials and Nanotechnology in Japan (ARIM)” of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Grant Number A-22-UT-0080. Funding Information: This study was financially supported by KAKENHI (JSPS, 20K22538). Prof. Takayuki Ishida (The University of Electro-Communications) kindly lent HPLC (Japan Analytical Industry, 1H + 1H GPC columns; a flow rate of 3.5 mL min) for the isolation of 1. The crystallography study for 1 was supported by “Advanced Research Infrastructure for Materials and Nanotechnology in Japan (ARIM)” of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Grant Number A-22-UT-0080. −1 Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",
year = "2023",
month = may,
day = "16",
doi = "10.1039/d3qo00591g",
language = "English",
volume = "10",
pages = "3193--3200",
journal = "Organic Chemistry Frontiers",
issn = "2052-4110",
publisher = "Royal Society of Chemistry",
number = "13",
}