Electrical and optical properties of wide-gap n-type Sn 2 Ta 2 O 7 films

Shunichi Suzuki, Keishi Nishio, Naoto Kikuchi

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Wide-gap n-type Sn 2 Ta 2 O 7 polycrystalline films were prepared by RF-magnetron sputtering followed by annealing in a reducing atmosphere (N 2 ). Sn 2 Ta 2 O 7 is known to show both p- and n-type conductivity. The electrical and optical properties of the films were examined as a function of annealing time. The bandgap of the film was estimated to be 2.7 or 3.2 eV assuming an indirect or direct transition, respectively. The electrical conductivity of the film at 300 K increased from 2.1 × 10 −8 S cm −1 (as-deposited) to a maximum of 2.1 S cm −1 (annealed for 14 h). The temperature dependence of the conductivity changed from semiconducting to degenerate semiconducting behavior with increasing annealing time, suggesting that oxygen vacancies were generated by the annealing in N 2 . From the temperature dependence of the mobility, it was found that neutral impurities were the dominant scattering centers for electron carriers.

本文言語English
論文番号031501
ジャーナルJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
37
3
DOI
出版ステータスPublished - 1 5月 2019

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