Crystal structure and Hirshfeld surface analysis of aqua(1H-imidazole-κN3)[N-(2-oxidobenzylidene)threonato-κ3O,N,O′]zinc(II)

Fumishi Yoshizawa; Anna Okui; Daisuke Nakane; Takashiro Akitsu

doi:10.1107/S2056989025002385

Crystal structure and Hirshfeld surface analysis of aqua(1H-imidazole-κN³)[N-(2-oxidobenzylidene)threonato-κ³O,N,O′]zinc(II)

Fumishi Yoshizawa, Anna Okui, Daisuke Nakane, Takashiro Akitsu

化学科

研究成果: Article › 査読

抄録

The title complex, [Zn(C11H11NO4)(C3H4N2)(H2O)], which includes a tridentate ligand, was synthesized from l-threonine and salicylaldehyde. One water molecule and one imidazole molecule additionally coordinate the zinc(II) center in a distorted trigonal-bipyramidal geometry. The crystal structure features N - H O and O - H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H/H H (50.7%) and O H/H O (25.0%) contacts.

本文言語	English
ページ（範囲）	332-335
ページ数	4
ジャーナル	Acta Crystallographica Section E: Crystallographic Communications
巻	81
DOI	https://doi.org/10.1107/S2056989025002385
出版ステータス	Published - 1 4月 2025

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10.1107/S2056989025002385

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「Crystal structure and Hirshfeld surface analysis of aqua(1H-imidazole-κN³)[N-(2-oxidobenzylidene)threonato-κ³O,N,O′]zinc(II)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "The title complex, [Zn(C11H11NO4)(C3H4N2)(H2O)], which includes a tridentate ligand, was synthesized from l-threonine and salicylaldehyde. One water molecule and one imidazole molecule additionally coordinate the zinc(II) center in a distorted trigonal-bipyramidal geometry. The crystal structure features N - H O and O - H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H/H H (50.7%) and O H/H O (25.0%) contacts.",

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T1 - Crystal structure and Hirshfeld surface analysis of aqua(1H-imidazole-κN3)[N-(2-oxidobenzylidene)threonato-κ3O,N,O′]zinc(II)

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AU - Okui, Anna

AU - Nakane, Daisuke

AU - Akitsu, Takashiro

PY - 2025/4/1

Y1 - 2025/4/1

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AB - The title complex, [Zn(C11H11NO4)(C3H4N2)(H2O)], which includes a tridentate ligand, was synthesized from l-threonine and salicylaldehyde. One water molecule and one imidazole molecule additionally coordinate the zinc(II) center in a distorted trigonal-bipyramidal geometry. The crystal structure features N - H O and O - H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H/H H (50.7%) and O H/H O (25.0%) contacts.

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KW - Hirshfeld surface analysis

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