Coexistence of conducting and magnetic electrons based on molecular π-electrons in the supramolecular conductor (Me-3,5-DIP)[Ni(dmit) 2]2

Yosuke Kosaka; Hiroshi M. Yamamoto; Akiko Nakao; Masafumi Tamura; Reizo Kato

doi:10.1021/ja0687825

Coexistence of conducting and magnetic electrons based on molecular π-electrons in the supramolecular conductor (Me-3,5-DIP)[Ni(dmit) ₂]₂

Yosuke Kosaka, Hiroshi M. Yamamoto, Akiko Nakao, Masafumi Tamura, Reizo Kato

先端物理学科

研究成果: Article › 査読

74 被引用数 (Scopus)

抄録

The supramolecular conductor (Me-3,5-DIP)[Ni(dmit)₂]₂, which was prepared by electrochemical oxidation, consists of two crystallographically independent layers of Ni(dmit)₂ anions (Layers I and II). The tight-binding band calculation suggests that Layer I is in a Mott insulating state to include localized spins, and Layer II displays two-dimensional metallic conduction. The coexistence of the two contrastive molecular π-electrons of Ni(dmit)₂ anions is evidenced by electrical resistivity and magnetic susceptibility measurements.

本文言語	English
ページ（範囲）	3054-3055
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	129
号	11
DOI	https://doi.org/10.1021/ja0687825
出版ステータス	Published - 21 3月 2007

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10.1021/ja0687825

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引用スタイル

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