Wet-carbonation-based Mineral Extraction and CO₂ Sequestration Using Concrete Waste Fines at a Low Temperature

This study investigates the wet carbonation of concrete fines with CO₂ and natural air gas bubbling in a carbonation system at low temperatures. After the air- and CO₂-wet carbonations, the properties of a solution and hydrated cement paste powder are determined. In the air and CO₂-wet carbonations, more Ca is extracted into the solution at a low temperature of 5°C. This high Ca concentration in the solution through air-wet carbonation primarily originates from the portlandite and unhydrated phases of the cement paste. Even in solutions with high pH values, the rehydration process and C–S–H decomposition occur simultaneously in air-wet carbonation. Moreover, CO₂-wet carbonation indicates that the decalcification of C–S–H occurs rapidly, even in the presence of portlandite. Air-wet carbonation presents a potential method for the direct air capture of CO₂ using concrete waste fines in a short period.