Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex

Makoto Tadokoro; Kiyoshi Isobe; Akira Miyazaki; Toshiaki Enoki; Kazuhiro Nakasuji

doi:10.1080/10587259608033673

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex

Makoto Tadokoro
, Kiyoshi Isobe
, Akira Miyazaki
, Toshiaki Enoki
, Kazuhiro Nakasuji

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two crystal structures of [Cu(tacn)(Hbim)](ClO₄)·MeOH (2) (tacn = 1,4,7-triazacyclononane) and [Cu(SalenNMe₂)(Hbim)]₂ (1) (salenNMe₂ = N-salicylidene-N′,N′-dimethylethylenediamine) have been determined. The structures are the first examples of a mononuclear complex containing monodeprotonated 2,2′-biimidazolate (Hbim^-) as a bidentate ligand.

Original language	English
Pages (from-to)	199-207
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume	278-279
DOIs	https://doi.org/10.1080/10587259608033673
Publication status	Published - 1996

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Tadokoro, M., Isobe, K., Miyazaki, A., Enoki, T., & Nakasuji, K. (1996). Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex. Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 278-279, 199-207. https://doi.org/10.1080/10587259608033673

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title = "Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex",

abstract = "Two crystal structures of [Cu(tacn)(Hbim)](ClO4)·MeOH (2) (tacn = 1,4,7-triazacyclononane) and [Cu(SalenNMe2)(Hbim)]2 (1) (salenNMe2 = N-salicylidene-N′,N′-dimethylethylenediamine) have been determined. The structures are the first examples of a mononuclear complex containing monodeprotonated 2,2′-biimidazolate (Hbim-) as a bidentate ligand.",

author = "Makoto Tadokoro and Kiyoshi Isobe and Akira Miyazaki and Toshiaki Enoki and Kazuhiro Nakasuji",

year = "1996",

doi = "10.1080/10587259608033673",

language = "English",

volume = "278-279",

pages = "199--207",

journal = "Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

Tadokoro, M, Isobe, K, Miyazaki, A, Enoki, T & Nakasuji, K 1996, 'Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex', Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, vol. 278-279, pp. 199-207. https://doi.org/10.1080/10587259608033673

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex. / Tadokoro, Makoto; Isobe, Kiyoshi; Miyazaki, Akira et al.
In: Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, Vol. 278-279, 1996, p. 199-207.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1

T2 - Dimer complex

AU - Tadokoro, Makoto

AU - Isobe, Kiyoshi

AU - Miyazaki, Akira

AU - Enoki, Toshiaki

AU - Nakasuji, Kazuhiro

PY - 1996

Y1 - 1996

N2 - Two crystal structures of [Cu(tacn)(Hbim)](ClO4)·MeOH (2) (tacn = 1,4,7-triazacyclononane) and [Cu(SalenNMe2)(Hbim)]2 (1) (salenNMe2 = N-salicylidene-N′,N′-dimethylethylenediamine) have been determined. The structures are the first examples of a mononuclear complex containing monodeprotonated 2,2′-biimidazolate (Hbim-) as a bidentate ligand.

AB - Two crystal structures of [Cu(tacn)(Hbim)](ClO4)·MeOH (2) (tacn = 1,4,7-triazacyclononane) and [Cu(SalenNMe2)(Hbim)]2 (1) (salenNMe2 = N-salicylidene-N′,N′-dimethylethylenediamine) have been determined. The structures are the first examples of a mononuclear complex containing monodeprotonated 2,2′-biimidazolate (Hbim-) as a bidentate ligand.

UR - https://www.scopus.com/pages/publications/0008084317

U2 - 10.1080/10587259608033673

DO - 10.1080/10587259608033673

M3 - Article

AN - SCOPUS:0008084317

SN - 1058-725X

VL - 278-279

SP - 199

EP - 207

JO - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

ER -

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 1: Dimer complex

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