Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4: Channel structures

Makoto Tadokoro; Kiyoshi Isobe; Kazuhiro Nakasuji

doi:10.1080/10587259608033676

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4: Channel structures

Makoto Tadokoro, Kiyoshi Isobe, Kazuhiro Nakasuji

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The crystal structure of [Ni(Hbim)₃](PTMA)·3MeOH (1) (Hbim^- = mono diprotonated 2,2′-biimidazolate and PTMA⁺ = phenyltrimethyl-ammonium cation) has been determined. The structure was consists of Ni(II) centers hexacoordinated by three 2,2′-biimidazolate (Hbim^-) ligands in an octahedral arrangement. The crystal packing structure of complex 1 forms channel structures having the hole about ∼9 Å along the c axis.

Original language	English
Pages (from-to)	217-220
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	278-279
DOIs	https://doi.org/10.1080/10587259608033676
Publication status	Published - 1996

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10.1080/10587259608033676

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@article{06638a5f59154071b42118b60b58b108,

title = "Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4: Channel structures",

abstract = "The crystal structure of [Ni(Hbim)3](PTMA)·3MeOH (1) (Hbim- = mono diprotonated 2,2′-biimidazolate and PTMA+ = phenyltrimethyl-ammonium cation) has been determined. The structure was consists of Ni(II) centers hexacoordinated by three 2,2′-biimidazolate (Hbim-) ligands in an octahedral arrangement. The crystal packing structure of complex 1 forms channel structures having the hole about ∼9 {\AA} along the c axis.",

author = "Makoto Tadokoro and Kiyoshi Isobe and Kazuhiro Nakasuji",

note = "Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas from the Ministry of Education, Science and Culture, Japan. The authors thank the Instrument Center, Institute for Molecular Science, for the use of a 4-Circle Single Crystal X-ray Diffractometer (ENRAF-NONIUS CAD4 FR538).",

year = "1996",

doi = "10.1080/10587259608033676",

language = "English",

volume = "278-279",

pages = "217--220",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4: Channel structures. / Tadokoro, Makoto; Isobe, Kiyoshi; Nakasuji, Kazuhiro.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 278-279, 1996, p. 217-220.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4

T2 - Channel structures

AU - Tadokoro, Makoto

AU - Isobe, Kiyoshi

AU - Nakasuji, Kazuhiro

N1 - Funding Information: This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas from the Ministry of Education, Science and Culture, Japan. The authors thank the Instrument Center, Institute for Molecular Science, for the use of a 4-Circle Single Crystal X-ray Diffractometer (ENRAF-NONIUS CAD4 FR538).

PY - 1996

Y1 - 1996

N2 - The crystal structure of [Ni(Hbim)3](PTMA)·3MeOH (1) (Hbim- = mono diprotonated 2,2′-biimidazolate and PTMA+ = phenyltrimethyl-ammonium cation) has been determined. The structure was consists of Ni(II) centers hexacoordinated by three 2,2′-biimidazolate (Hbim-) ligands in an octahedral arrangement. The crystal packing structure of complex 1 forms channel structures having the hole about ∼9 Å along the c axis.

AB - The crystal structure of [Ni(Hbim)3](PTMA)·3MeOH (1) (Hbim- = mono diprotonated 2,2′-biimidazolate and PTMA+ = phenyltrimethyl-ammonium cation) has been determined. The structure was consists of Ni(II) centers hexacoordinated by three 2,2′-biimidazolate (Hbim-) ligands in an octahedral arrangement. The crystal packing structure of complex 1 forms channel structures having the hole about ∼9 Å along the c axis.

UR - https://www.scopus.com/pages/publications/4143131055

U2 - 10.1080/10587259608033676

DO - 10.1080/10587259608033676

M3 - Article

AN - SCOPUS:4143131055

SN - 1058-725X

VL - 278-279

SP - 217

EP - 220

JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

ER -

Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems. Part 4: Channel structures

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