Thermodynamic properties of liquid Na-Pb alloys

S. Matsunaga, T. Ishiguro, S. Tamaki

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

The EMF of Na in the liquid Na-Pb system has been measured as a function of temperature using a concentration cell. The associated thermodynamic quantities of mixing Delta G, Delta S and Delta H are obtained, and the deviation from the additivity of specific heat, Delta Cp, is also obtained. The curve of the concentration-concentration fluctuation in the long-wavelength limit, SCC(0), obtained from Delta G, shows three kinds of atomic associations at the compositions of Na4Pb, NaPb and NaPb, respectively.

Original languageEnglish
Article number009
Pages (from-to)587-595
Number of pages9
JournalJournal of Physics F: Metal Physics
Volume13
Issue number3
DOIs
Publication statusPublished - 1983

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