Synthesis of dibenzoheteropines of group 13-16 elements via ring-closing metathesis

Takanori Matsuda, Shinya Sato

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The ring-closing metathesis (RCM) of bis(2-vinylphenyl)silanes in the presence of the second-generation Hoveyda-Grubbs catalyst in toluene at 100 C afforded dibenzo[b,f]silepines in excellent yields. Other dibenzoheteropines of group 13-16 elements were also prepared via the RCM of the corresponding heteroatom-tethered dienes.

Original languageEnglish
Pages (from-to)3329-3335
Number of pages7
JournalJournal of Organic Chemistry
Volume78
Issue number7
DOIs
Publication statusPublished - 5 Apr 2013

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