Photochemical generation of superbases from carboxylates consisting of phthalimidoacetic acid derivatives and superbases

Koji Arimitsu, Ken Fukuda, Nobuhiko Sakai

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

We have developed simple and powerful photobase generators capable of highly efficient production of superbases. These photobase generators were prepared by simply mixing phthalimidoacetic acid derivatives with the corresponding superbases. The use of photobase generators enabled anionic UV curing at lower temperatures, in contrast to previous anionic UV curing materials that required heat treatment above 150 °C after UV irradiation. The cured films showed no volume shrinkage.

Original languageEnglish
Pages (from-to)831-833
Number of pages3
JournalChemistry Letters
Volume43
Issue number6
DOIs
Publication statusPublished - 1 Jan 2014

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