Optical study on [M(dmit)2] salts

H. Tajima; T. Naito; M. Tamura; A. Takahashi; S. Toyoda; A. Kobayashi; H. Kuroda; R. Kato; H. Kobayashi; R. A. Clark; A. E. Underhill

doi:10.1016/0379-6779(91)91396-R

Optical study on [M(dmit)2] salts

H. Tajima
, T. Naito
, M. Tamura
, A. Takahashi
, S. Toyoda
, A. Kobayashi
, H. Kuroda
, R. Kato
, H. Kobayashi
, R. A. Clark
, A. E. Underhill

Department of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Visible and infrared reflectance spectra were observed on single crystals of [M(dmit)2] salts. The band parameters of Me₄N[Ni(dmit)2]2 were obtained from the reflectance spectra and compared with the results of thermoelectric power measurements. The direct experimental evidences showing the "LUMO-HUMO energy level inversion" are presented for Cs[Pd(dmit)2]2, Me₄As[Pd(dmit)2]2, and Me₄N[Pt(dmit)2]2.

Original language	English
Pages (from-to)	2417-2421
Number of pages	5
Journal	Synthetic Metals
Volume	42
Issue number	3
DOIs	https://doi.org/10.1016/0379-6779(91)91396-R
Publication status	Published - 29 May 1991

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@article{8361188a4559441f821a62a5495467bb,

title = "Optical study on [M(dmit)2] salts",

abstract = "Visible and infrared reflectance spectra were observed on single crystals of [M(dmit)2] salts. The band parameters of Me4N[Ni(dmit)2]2 were obtained from the reflectance spectra and compared with the results of thermoelectric power measurements. The direct experimental evidences showing the {"}LUMO-HUMO energy level inversion{"} are presented for Cs[Pd(dmit)2]2, Me4As[Pd(dmit)2]2, and Me4N[Pt(dmit)2]2.",

author = "H. Tajima and T. Naito and M. Tamura and A. Takahashi and S. Toyoda and A. Kobayashi and H. Kuroda and R. Kato and H. Kobayashi and Clark, \{R. A.\} and Underhill, \{A. E.\}",

year = "1991",

month = may,

day = "29",

doi = "10.1016/0379-6779(91)91396-R",

language = "English",

volume = "42",

pages = "2417--2421",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Optical study on [M(dmit)2] salts

AU - Tajima, H.

AU - Naito, T.

AU - Tamura, M.

AU - Takahashi, A.

AU - Toyoda, S.

AU - Kobayashi, A.

AU - Kuroda, H.

AU - Kato, R.

AU - Kobayashi, H.

AU - Clark, R. A.

AU - Underhill, A. E.

PY - 1991/5/29

Y1 - 1991/5/29

N2 - Visible and infrared reflectance spectra were observed on single crystals of [M(dmit)2] salts. The band parameters of Me4N[Ni(dmit)2]2 were obtained from the reflectance spectra and compared with the results of thermoelectric power measurements. The direct experimental evidences showing the "LUMO-HUMO energy level inversion" are presented for Cs[Pd(dmit)2]2, Me4As[Pd(dmit)2]2, and Me4N[Pt(dmit)2]2.

AB - Visible and infrared reflectance spectra were observed on single crystals of [M(dmit)2] salts. The band parameters of Me4N[Ni(dmit)2]2 were obtained from the reflectance spectra and compared with the results of thermoelectric power measurements. The direct experimental evidences showing the "LUMO-HUMO energy level inversion" are presented for Cs[Pd(dmit)2]2, Me4As[Pd(dmit)2]2, and Me4N[Pt(dmit)2]2.

UR - https://www.scopus.com/pages/publications/0026154587

U2 - 10.1016/0379-6779(91)91396-R

DO - 10.1016/0379-6779(91)91396-R

M3 - Article

AN - SCOPUS:0026154587

SN - 0379-6779

VL - 42

SP - 2417

EP - 2421

JO - Synthetic Metals

JF - Synthetic Metals

IS - 3

ER -

Optical study on [M(dmit)2] salts

Abstract

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