Mixed-valence states stabilized by proton transfer in a hydrogen-bonded biimidazolate rhenium dimer

Makoto Tadokoro; Tomonori Inoue; Satoru Tamaki; Keisuke Fujii; Kazuo Isogai; Hiroshi Nakazawa; Sadamu Takeda; Kiyoshi Isobe; Nobuaki Koga; Akio Ichimura; Kazuhiro Nakasuji

doi:10.1002/anie.200701277

Mixed-valence states stabilized by proton transfer in a hydrogen-bonded biimidazolate rhenium dimer

Makoto Tadokoro
, Tomonori Inoue
, Satoru Tamaki
, Keisuke Fujii
, Kazuo Isogai
, Hiroshi Nakazawa
, Sadamu Takeda
, Kiyoshi Isobe
, Nobuaki Koga
, Akio Ichimura
, Kazuhiro Nakasuji

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Di-Re straits: Synchronized motion of protons and electrons, as shown in the scheme, has been observed in a hydrogen-bonded Re dimer complex. The mixed-valence states obtained by electrochemical redox reactions are stabilized by proton transfer within the dual hydrogen-bonding site between 2,2′-biimidazolate ligands. (Chemical Equation Presented).

Original language	English
Pages (from-to)	5938-5942
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	31
DOIs	https://doi.org/10.1002/anie.200701277
Publication status	Published - 2007

Keywords

Coordination chemistry
Electron transfer
Hydrogen bonds
Proton transfer
Supramolecular chemistry

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10.1002/anie.200701277

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title = "Mixed-valence states stabilized by proton transfer in a hydrogen-bonded biimidazolate rhenium dimer",

abstract = "Di-Re straits: Synchronized motion of protons and electrons, as shown in the scheme, has been observed in a hydrogen-bonded Re dimer complex. The mixed-valence states obtained by electrochemical redox reactions are stabilized by proton transfer within the dual hydrogen-bonding site between 2,2′-biimidazolate ligands. (Chemical Equation Presented).",

keywords = "Coordination chemistry, Electron transfer, Hydrogen bonds, Proton transfer, Supramolecular chemistry",

author = "Makoto Tadokoro and Tomonori Inoue and Satoru Tamaki and Keisuke Fujii and Kazuo Isogai and Hiroshi Nakazawa and Sadamu Takeda and Kiyoshi Isobe and Nobuaki Koga and Akio Ichimura and Kazuhiro Nakasuji",

year = "2007",

doi = "10.1002/anie.200701277",

language = "English",

volume = "46",

pages = "5938--5942",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Mixed-valence states stabilized by proton transfer in a hydrogen-bonded biimidazolate rhenium dimer

AU - Tadokoro, Makoto

AU - Inoue, Tomonori

AU - Tamaki, Satoru

AU - Fujii, Keisuke

AU - Isogai, Kazuo

AU - Nakazawa, Hiroshi

AU - Takeda, Sadamu

AU - Isobe, Kiyoshi

AU - Koga, Nobuaki

AU - Ichimura, Akio

AU - Nakasuji, Kazuhiro

PY - 2007

Y1 - 2007

N2 - Di-Re straits: Synchronized motion of protons and electrons, as shown in the scheme, has been observed in a hydrogen-bonded Re dimer complex. The mixed-valence states obtained by electrochemical redox reactions are stabilized by proton transfer within the dual hydrogen-bonding site between 2,2′-biimidazolate ligands. (Chemical Equation Presented).

AB - Di-Re straits: Synchronized motion of protons and electrons, as shown in the scheme, has been observed in a hydrogen-bonded Re dimer complex. The mixed-valence states obtained by electrochemical redox reactions are stabilized by proton transfer within the dual hydrogen-bonding site between 2,2′-biimidazolate ligands. (Chemical Equation Presented).

KW - Coordination chemistry

KW - Electron transfer

KW - Hydrogen bonds

KW - Proton transfer

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/34547814242

U2 - 10.1002/anie.200701277

DO - 10.1002/anie.200701277

M3 - Article

C2 - 17614342

AN - SCOPUS:34547814242

SN - 1433-7851

VL - 46

SP - 5938

EP - 5942

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 31

ER -

Mixed-valence states stabilized by proton transfer in a hydrogen-bonded biimidazolate rhenium dimer

Abstract

Keywords

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