Infrared-induced reaction on MoO3 using a tunable infrared free electron laser

Golam Moula; Shinsuke Sato; Katsumi Irokawa; Hironobu Niimi; Shushi Suzuki; Kiyotaka Asakura; Haruo Kuroda

doi:10.1246/bcsj.81.836

Infrared-induced reaction on MoO₃ using a tunable infrared free electron laser

Golam Moula, Shinsuke Sato, Katsumi Irokawa, Hironobu Niimi, Shushi Suzuki, Kiyotaka Asakura, Haruo Kuroda

Department of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We observed the IR-induced reaction of C₂H₅OH on MoO₃ using a pulsed and tunable infrared free electron laser (IR-FEL). The IR-FEL-induced reaction showed wavelength dependency and requires light stronger than a certain threshold level. The C₂H₅OH was converted mainly to C₂H₄ only when the MoO₃ was irradiated with focused IR-FEL at 967 and 814 cm^-1 corresponding to Mo=O stretching modes, whereas IR light at 1200 cm^-1 induced no reaction. The origin of this IR-FEL-induced reaction is discussed.

Original language	English
Pages (from-to)	836-842
Number of pages	7
Journal	Bulletin of the Chemical Society of Japan
Volume	81
Issue number	7
DOIs	https://doi.org/10.1246/bcsj.81.836
Publication status	Published - 15 Jul 2008

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title = "Infrared-induced reaction on MoO3 using a tunable infrared free electron laser",

abstract = "We observed the IR-induced reaction of C2H5OH on MoO3 using a pulsed and tunable infrared free electron laser (IR-FEL). The IR-FEL-induced reaction showed wavelength dependency and requires light stronger than a certain threshold level. The C2H5OH was converted mainly to C2H4 only when the MoO3 was irradiated with focused IR-FEL at 967 and 814 cm-1 corresponding to Mo=O stretching modes, whereas IR light at 1200 cm-1 induced no reaction. The origin of this IR-FEL-induced reaction is discussed.",

author = "Golam Moula and Shinsuke Sato and Katsumi Irokawa and Hironobu Niimi and Shushi Suzuki and Kiyotaka Asakura and Haruo Kuroda",

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T1 - Infrared-induced reaction on MoO3 using a tunable infrared free electron laser

AU - Moula, Golam

AU - Sato, Shinsuke

AU - Irokawa, Katsumi

AU - Niimi, Hironobu

AU - Suzuki, Shushi

AU - Asakura, Kiyotaka

AU - Kuroda, Haruo

PY - 2008/7/15

Y1 - 2008/7/15

N2 - We observed the IR-induced reaction of C2H5OH on MoO3 using a pulsed and tunable infrared free electron laser (IR-FEL). The IR-FEL-induced reaction showed wavelength dependency and requires light stronger than a certain threshold level. The C2H5OH was converted mainly to C2H4 only when the MoO3 was irradiated with focused IR-FEL at 967 and 814 cm-1 corresponding to Mo=O stretching modes, whereas IR light at 1200 cm-1 induced no reaction. The origin of this IR-FEL-induced reaction is discussed.

AB - We observed the IR-induced reaction of C2H5OH on MoO3 using a pulsed and tunable infrared free electron laser (IR-FEL). The IR-FEL-induced reaction showed wavelength dependency and requires light stronger than a certain threshold level. The C2H5OH was converted mainly to C2H4 only when the MoO3 was irradiated with focused IR-FEL at 967 and 814 cm-1 corresponding to Mo=O stretching modes, whereas IR light at 1200 cm-1 induced no reaction. The origin of this IR-FEL-induced reaction is discussed.

UR - https://www.scopus.com/pages/publications/58149242686

U2 - 10.1246/bcsj.81.836

DO - 10.1246/bcsj.81.836

M3 - Article

AN - SCOPUS:58149242686

SN - 0009-2673

VL - 81

SP - 836

EP - 842

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 7

ER -

Infrared-induced reaction on MoO₃ using a tunable infrared free electron laser

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