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Inclusion compounds of K+-crown ether derivatives introduced by trisbiimidazolate nickel(II) complex with large channel structures

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Abstract

[Ni(Hbim)3][K-crypland] (K-cryptand = potassium crypt and monocation: Hbim = mono-deprotonated 2,2′-biimidazolatc] is synthesized and its crystal structure is characterized by X-ray crystal analysis. (Crystal data: motmclinic, C2/c (No. 15), a = 18.966(2) Å, b = 19.059(2) Å, c = 25.469(2) Å, β= 103.201(8)̊, V= 8962(1) Å3 Z= 8) It has a unique channel structure built up by slacking two-dimensional honeycomb sheets.

Original languageEnglish
Pages (from-to)385-390
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume306
DOIs
Publication statusPublished - 1997

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