Hydrothermal synthesis and visible-light-driven photocatalytic activity of allophane-wakefieldite-(Ce) composite

Mirabbos Hojamberdiev, Yuki Makinose, Ken Ichi Katsumata, Toshihiro Isobe, Nobuhiro Matsushita, Kiyoshi Okada

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

In this study, highly adsorptive mechanically-mixed and as-synthesized allophane- wakefieldite-(Ce) composites were prepared by mechanical mixing and hydrothermal synthesis, respectively. The results from X-ray diffraction and Raman spectroscopy analyses show that the mechanically-mixed composite has higher crystallinity than the as-synthesized composite. The nanoparticles of wakefieldite-(Ce) were homogenously distributed with allophane in the assynthesized composite. The specific surface areas of the mechanically-mixed and as-synthesized composites are 164 m2/g and 191 m2/g, respectively. The photocatalytic activity of the samples was evaluated for the degradation of acetaldehyde (AcH) gas under visible light. Both composites demonstrated higher photocatalytic activity than individual wakefieldite-(Ce) and allophane because allophane in the composites played an important role in the adsorption of acetaldehyde gas molecules and the mediation between the gas phase and the wakefieldite-(Ce) surface.

Original languageEnglish
Title of host publicationAdvanced Materials Science and Technology - ICAMST 2013
PublisherTrans Tech Publications
Pages545-548
Number of pages4
ISBN (Print)9783038350316
DOIs
Publication statusPublished - 2014
Event2013 International Conference on Advanced Materials Science and Technology, ICAMST 2013 - Yogyakarta, Indonesia
Duration: 17 Sept 201318 Sept 2013

Publication series

NameAdvanced Materials Research
Volume896
ISSN (Print)1022-6680

Conference

Conference2013 International Conference on Advanced Materials Science and Technology, ICAMST 2013
Country/TerritoryIndonesia
CityYogyakarta
Period17/09/1318/09/13

Keywords

  • Acetaldehyde
  • Allophane
  • Clay minerals
  • Composite
  • Photodegradation
  • Visible light
  • Wakefieldite-(Ce)

Fingerprint

Dive into the research topics of 'Hydrothermal synthesis and visible-light-driven photocatalytic activity of allophane-wakefieldite-(Ce) composite'. Together they form a unique fingerprint.

Cite this