Electrochemical impedance simulation of branch structure porous carbon electrode using transmission line model

Isao Shitanda, Seiya Tsujimura, Hiroki Yanai, Yoshinao Hoshi, Masayuki Itagaki

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6 Citations (Scopus)

Abstract

Impedance simulation was performed for analysis of a branch structure porous carbon electrode composed of macropores and mesopores. Theoretical equations were derived by introducing a new branch structure transmission line model, in which the charge-transfer reactions in the pores are considered. The loci of the straight line with angles at 22.5° and semicircle were observed in the high and low frequency ranges. It was found that the charge-transfer resistance in the mesopore interface had no influence on the loci of the straight line.

Original languageEnglish
Pages (from-to)335-338
Number of pages4
JournalElectrochemistry
Volume83
Issue number5
DOIs
Publication statusPublished - 5 May 2015

Keywords

  • Branch Structure Electrode
  • Electrochemical Impedance Spectroscopy Simulation
  • Macropore
  • Mesopore

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