Crystal structure of 3,6-dihydroxy-4,5-dimethylbenzene-1,2-dicarbaldehyde

Shu Yamazaki; Kazuki Nishiyama; Shiomi Yagi; Tomoyuki Haraguchi; Takashiro Akitsu

doi:10.1107/S2056989018012495

Crystal structure of 3,6-dihydroxy-4,5-dimethylbenzene-1,2-dicarbaldehyde

Shu Yamazaki, Kazuki Nishiyama, Shiomi Yagi, Tomoyuki Haraguchi, Takashiro Akitsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, C 10 H 10 O 4, was synthesized from tetramethyl-1,4-benzoquinone. In the crystal, the almost planar molecule (r.m.s. deviation = 0.024 Å) forms intramolecular hydrogen bonds between the aldehyde and hydroxy groups and exhibits C 2v symmetry. This achiral molecule crystallizes in the chiral space group P2 1 with intermolecular O - H⋯O and C - H⋯O hydrogen bonding and C - H⋯ and C=O⋯π interactions stabilizing the crystal packing.

Original language	English
Pages (from-to)	1424-1426
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	74
DOIs	https://doi.org/10.1107/S2056989018012495
Publication status	Published - 2018

Keywords

alkylating agents
chiral crystallization
crystal structure

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title = "Crystal structure of 3,6-dihydroxy-4,5-dimethylbenzene-1,2-dicarbaldehyde",

abstract = "The title compound, C 10 H 10 O 4, was synthesized from tetramethyl-1,4-benzoquinone. In the crystal, the almost planar molecule (r.m.s. deviation = 0.024 {\AA}) forms intramolecular hydrogen bonds between the aldehyde and hydroxy groups and exhibits C 2v symmetry. This achiral molecule crystallizes in the chiral space group P2 1 with intermolecular O - H⋯O and C - H⋯O hydrogen bonding and C - H⋯ and C=O⋯π interactions stabilizing the crystal packing.",

keywords = "alkylating agents, chiral crystallization, crystal structure",

author = "Shu Yamazaki and Kazuki Nishiyama and Shiomi Yagi and Tomoyuki Haraguchi and Takashiro Akitsu",

note = "Publisher Copyright: {\textcopyright} {\textcopyright} Yamazaki et al. 2018.",

year = "2018",

doi = "10.1107/S2056989018012495",

language = "English",

volume = "74",

pages = "1424--1426",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Crystal structure of 3,6-dihydroxy-4,5-dimethylbenzene-1,2-dicarbaldehyde

AU - Yamazaki, Shu

AU - Nishiyama, Kazuki

AU - Yagi, Shiomi

AU - Haraguchi, Tomoyuki

AU - Akitsu, Takashiro

N1 - Publisher Copyright: © © Yamazaki et al. 2018.

PY - 2018

Y1 - 2018

N2 - The title compound, C 10 H 10 O 4, was synthesized from tetramethyl-1,4-benzoquinone. In the crystal, the almost planar molecule (r.m.s. deviation = 0.024 Å) forms intramolecular hydrogen bonds between the aldehyde and hydroxy groups and exhibits C 2v symmetry. This achiral molecule crystallizes in the chiral space group P2 1 with intermolecular O - H⋯O and C - H⋯O hydrogen bonding and C - H⋯ and C=O⋯π interactions stabilizing the crystal packing.

AB - The title compound, C 10 H 10 O 4, was synthesized from tetramethyl-1,4-benzoquinone. In the crystal, the almost planar molecule (r.m.s. deviation = 0.024 Å) forms intramolecular hydrogen bonds between the aldehyde and hydroxy groups and exhibits C 2v symmetry. This achiral molecule crystallizes in the chiral space group P2 1 with intermolecular O - H⋯O and C - H⋯O hydrogen bonding and C - H⋯ and C=O⋯π interactions stabilizing the crystal packing.

KW - alkylating agents

KW - chiral crystallization

KW - crystal structure

UR - https://www.scopus.com/pages/publications/85054562183

U2 - 10.1107/S2056989018012495

DO - 10.1107/S2056989018012495

M3 - Article

AN - SCOPUS:85054562183

SN - 2056-9890

VL - 74

SP - 1424

EP - 1426

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of 3,6-dihydroxy-4,5-dimethylbenzene-1,2-dicarbaldehyde

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Keywords

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