Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN3)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j3O,N,O0]copper(II)

Ai Kaneda; Soma Suzuki; Daisuke Nakane; Yukiyasu Kashiwagi; Takashiro Akitsu

doi:10.1107/S2056989024002986

Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN³)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j³O,N,O⁰]copper(II)

Ai Kaneda, Soma Suzuki, Daisuke Nakane, Yukiyasu Kashiwagi, Takashiro Akitsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title copper(II) complex, [Cu(C₁₈H₁₉N₃O₃)(C₃H₄N₂)], consists of a tridentate ligand synthesized from l-leucine and azobenzene-salicylaldehyde. One imidazole molecule is additionally coordinated to the copper(II) ion in the equatorial plane. The crystal structure features N—H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H (52.0%) and C H/H C (17.9%) contacts.

Original language	English
Pages (from-to)	468-471
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	80
Issue number	Pt 5
DOIs	https://doi.org/10.1107/S2056989024002986
Publication status	Published - 1 Apr 2024

Keywords

Azobenzene
Hirshfeld analysis
Schiff base ligand
amino acid
copper(II) complex
crystal structure

Access to Document

10.1107/S2056989024002986

Cite this

Kaneda, A., Suzuki, S., Nakane, D., Kashiwagi, Y., & Akitsu, T. (2024). Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN³)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j³O,N,O⁰]copper(II). Acta Crystallographica Section E: Crystallographic Communications, 80(Pt 5), 468-471. https://doi.org/10.1107/S2056989024002986

@article{87e230c726a14c4ba94628b245d0618b,

title = "Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN3)[4-methyl-2-(\{[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene\}amino)pentanoate-j3O,N,O0]copper(II)",

abstract = "The title copper(II) complex, [Cu(C18H19N3O3)(C3H4N2)], consists of a tridentate ligand synthesized from l-leucine and azobenzene-salicylaldehyde. One imidazole molecule is additionally coordinated to the copper(II) ion in the equatorial plane. The crystal structure features N—H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H (52.0\%) and C H/H C (17.9\%) contacts.",

keywords = "Azobenzene, Hirshfeld analysis, Schiff base ligand, amino acid, copper(II) complex, crystal structure",

author = "Ai Kaneda and Soma Suzuki and Daisuke Nakane and Yukiyasu Kashiwagi and Takashiro Akitsu",

year = "2024",

month = apr,

day = "1",

doi = "10.1107/S2056989024002986",

language = "English",

volume = "80",

pages = "468--471",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

number = "Pt 5",

}

Kaneda, A, Suzuki, S, Nakane, D, Kashiwagi, Y & Akitsu, T 2024, 'Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN³)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j³O,N,O⁰]copper(II)', Acta Crystallographica Section E: Crystallographic Communications, vol. 80, no. Pt 5, pp. 468-471. https://doi.org/10.1107/S2056989024002986

Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN³)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j³O,N,O⁰]copper(II). / Kaneda, Ai; Suzuki, Soma; Nakane, Daisuke et al.
In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 80, No. Pt 5, 01.04.2024, p. 468-471.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN3)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j3O,N,O0]copper(II)

AU - Kaneda, Ai

AU - Suzuki, Soma

AU - Nakane, Daisuke

AU - Kashiwagi, Yukiyasu

AU - Akitsu, Takashiro

PY - 2024/4/1

Y1 - 2024/4/1

N2 - The title copper(II) complex, [Cu(C18H19N3O3)(C3H4N2)], consists of a tridentate ligand synthesized from l-leucine and azobenzene-salicylaldehyde. One imidazole molecule is additionally coordinated to the copper(II) ion in the equatorial plane. The crystal structure features N—H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H (52.0%) and C H/H C (17.9%) contacts.

AB - The title copper(II) complex, [Cu(C18H19N3O3)(C3H4N2)], consists of a tridentate ligand synthesized from l-leucine and azobenzene-salicylaldehyde. One imidazole molecule is additionally coordinated to the copper(II) ion in the equatorial plane. The crystal structure features N—H O hydrogen bonds. A Hirshfeld surface analysis indicates that the most important contributions to the packing are from H H (52.0%) and C H/H C (17.9%) contacts.

KW - Azobenzene

KW - Hirshfeld analysis

KW - Schiff base ligand

KW - amino acid

KW - copper(II) complex

KW - crystal structure

UR - https://www.scopus.com/pages/publications/85192859784

U2 - 10.1107/S2056989024002986

DO - 10.1107/S2056989024002986

M3 - Article

AN - SCOPUS:85192859784

SN - 2056-9890

VL - 80

SP - 468

EP - 471

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - Pt 5

ER -

Crystal structure and Hirshfeld surface analysis of (1H-imidazole-jN³)[4-methyl-2-({[2-oxido-5-(2-phenyldiazen-1-yl)phenyl]methylidene}amino)pentanoate-j³O,N,O⁰]copper(II)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this