Azobenzene-tethered bis(trityl alcohol) as a photoswitchable cooperative acid catalyst for Morita-Baylis-Hillman reactions

Tatsushi Imahori, Ryo Yamaguchi, Seiji Kurihara

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Incorporation of an azobenzene core into tethered bis(trityl alcohol) allows the photoswitchable arrangement of the two trityl alcohol units through photoisomerization of azobenzene. The differently arranged trityl alcohol units change their cooperative function to reflect the positional relationships, and thus, the activity as a cooperative acid can be controlled by light stimuli (see figure).

Original languageEnglish
Pages (from-to)10802-10807
Number of pages6
JournalChemistry - A European Journal
Volume18
Issue number35
DOIs
Publication statusPublished - 27 Aug 2012

Keywords

  • acid catalysts
  • azo compounds
  • cooperative catalysts
  • Morita-Baylis-Hillman reaction
  • photochemistry

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