Anion-π interaction at the solid/water interfaces

Masaaki Akamatsu, Ayumi Kimura, Koji Yamanaga, Kenichi Sakai, Hideki Sakai

Research output: Contribution to journalArticlepeer-review

Abstract

Anion-π interaction has been found to play a key role in interfacial phenomena. In this study, we evaluated the anion-π interactions at the solid/water interface. Anion adsorption originating from anion-π interaction at the interfaces followed the hydration energy and the presence of conjugated systems of the anions by the QCM measurements. Force curve measurements revealed that the single-molecule force of anion-π interaction between an NDI unit and the negatively charged surface of the cantilever was ∼40 pN. To the best of our knowledge, this is the first example of obtaining a single-molecule force for anion-π interactions.

Original languageEnglish
Pages (from-to)4650-4653
Number of pages4
JournalChemical Communications
Volume57
Issue number38
DOIs
Publication statusPublished - 11 May 2021

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