Amplification of luminescence of stable radicals by coordination to NHC-gold(i) complex

Yohei Hattori, Ryota Kitajima, Ryota Matsuoka, Tetsuro Kusamoto, Hiroshi Nishihara, Kingo Uchida

Research output: Contribution to journalArticlepeer-review

Abstract

The luminescence of stable radicals can be enhanced by coordination to metal complexes. The 4% fluorescence quantum yield of (3,5-difluoro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical (F2PyBTM) in dichloromethane was enhanced up to 36% by coordination to AuI with N-heterocyclic carbene ligand, which is a record for metal-radical complexes. This journal is

Original languageEnglish
Pages (from-to)2560-2563
Number of pages4
JournalChemical Communications
Volume58
Issue number15
DOIs
Publication statusPublished - 21 Feb 2022

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