A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

Daisuke Nakane, Shin Ich Kuwasako, Michiharu Tsuge, Minoru Kubo, Yasuhiro Funahashi, Tomohiro Ozawa, Takashi Ogura, Hideki Masuda

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

The structure around the metal centre of a Ni(ii) complex with an N 2S2 square-planar geometry, 1, prepared as a model compound of the NiSOD active site was drastically changed upon addition of potassium superoxide (KO2).

Original languageEnglish
Pages (from-to)2142-2144
Number of pages3
JournalChemical Communications
Volume46
Issue number12
DOIs
Publication statusPublished - 2010

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