A high-conductivity crystal containing a copper(I) coordination polymer bridged by the organic acceptor TANC

Makoto Tadokoro, Syuma Yasuzuka, Masaharu Nakamura, Takumi Shinoda, Toshinori Tatenuma, Minoru Mitsumi, Yoshiki Ozawa, Koshiro Toriumi, Harukazu Yoshino, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Takehiko Mori, Keizo Murata

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Abstract

Molecular conductors: A new, modifiable electron acceptor with a 5,6,11,12-tetraazanaphthacene (TANC) framework was introduced in Cu I-TANC coordination polymers (see picture). The conduction mechanism of a high-conductivity crystal constructed from these polymers can be described as 1D variable-range hopping based on the disordered F- ions. (Figure Presented).

Original languageEnglish
Pages (from-to)5144-5147
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number31
DOIs
Publication statusPublished - 4 Aug 2006

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Keywords

  • Conducting materials
  • Copper
  • Crystal engineering
  • High-pressure chemistry
  • Supramolecular chemistry

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